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1

Recent Developments in Negishi Cross-Coupling Reactions

Haas, Diana, Hammann, Jeffrey M., Greiner, Robert, Knochel, Paul

Journal:

Year:

2016

Language:

english

File:

PDF, 2.02 MB

english, 2016

2

Classics in Total Synthesis. Targets, Strategies, Methods. Von K. C. Nicolaou und E. J. Sorensen. VCH, Weinheim, 1996. 798 S., geb./ Broschur 128.00 DM/78.00 DM. - ISBN 3-527-29284-5/3-527-29231-4

Journal:

Angewandte Chemie

Year:

1996

Language:

german

File:

PDF, 164 KB

german, 1996

3

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

Dr. Benjamin Haag, Dr. Marc Mosrin, Prof. Dr. Hiriyakkanavar Ila, Dr. Vladimir Malakhov, Prof. Dr. Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2011

Language:

english

File:

PDF, 2.09 MB

english, 2011

4

Cross-Coupling Reactions. A Practical Guide. Edited by N. Miyaura

Journal:

Advanced Synthesis & Catalysis

Year:

2003

Language:

english

File:

PDF, 28 KB

english, 2003

5

Highly Functionalized Organomagnesium Reagents Prepared through Halogen–Metal Exchange

Paul Knochel, Wolfgang Dohle, Nina Gommermann, Florian F. Kneisel, Felix Kopp, Tobias Korn, Ioannis Sapountzis, Viet Anh Vu

Journal:

Angewandte Chemie International Edition

Year:

2003

Language:

english

File:

PDF, 672 KB

english, 2003

6

Aluminum Bases for the Highly Chemoselective Preparation of Aryl and Heteroaryl Aluminum Compounds

Stefan H. Wunderlich, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2009

Language:

english

File:

PDF, 323 KB

english, 2009

7

Direct Zincation of Functionalized Aromatics and Heterocycles by Using a Magnesium Base in the Presence of ZnCl2

Zhibing Dong, Giuliano C. Clososki, Stefan H. Wunderlich, Andreas Unsinn, Jinshan Li, Paul Knochel

Journal:

Chemistry - A European Journal

Year:

2009

Language:

english

File:

PDF, 363 KB

english, 2009

8

Preparations and Reactions of SF5-Substituted Aryl and Heteroaryl Derivatives via Mg and Zn Organometallics

Annette Frischmuth, Andreas Unsinn, Klaus Groll, Dr. Heinz Stadtmüller, Prof. Dr. Paul Knochel

Journal:

Chemistry - A European Journal

Year:

2012

Language:

english

File:

PDF, 336 KB

english, 2012

9

TMPZnCl·LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics

Mosrin, Marc, Knochel, Paul

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 125 KB

english, 2009

10

Improved Air-Stable Solid Aromatic and Heterocyclic Zinc Reagents by Highly Selective Metalations for Negishi Cross-Couplings

Dr. Christos I. Stathakis, M. Sc. Sebastian Bernhardt, B. Sc. Valentin Quint, Prof. Dr. Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2012

Language:

english

File:

PDF, 546 KB

english, 2012

11

Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl·LiCl

Mosrin, Marc, Knochel, Paul

Journal:

Organic Letters

Year:

2008

Language:

english

File:

PDF, 123 KB

english, 2008

12

Continuous Preparation of Arylmagnesium Reagents in Flow with Inline IR Monitoring

Brodmann, Tobias, Koos, Peter, Metzger, Albrecht, Knochel, Paul, Ley, Steven V.

Journal:

Organic Process Research & Development

Year:

2012

Language:

english

File:

PDF, 1.14 MB

english, 2012

13

Comprehensive Organic Synthesis || Organozinc, Organocadmium and Organomercury Reagents

Year:

1991

Language:

english

File:

PDF, 2.15 MB

english, 1991

14

Organic Reactions || Preparation and Applications of Functionalized Organozinc Compounds

Year:

2004

File:

PDF, 4.09 MB

2004

15

Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations

Despotopoulou, Christina, Klier, Lydia, Knochel, Paul

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 445 KB

english, 2009

16

50 Years SYNTHESIS – Golden Anniversary Issue

Journal:

Year:

2019

Language:

english

File:

PDF, 11.66 MB

english, 2019

17

Cobalt-Catalyzed Cross-Couplings and Electrophilic Aminations using Organozinc Pivalates

Lutter, Ferdinand Hermann, Graßl, Simon, Grokenberger, Lucie, Hofmayer, Maximilian Simon, Chen, Yi-Hung, Knochel, Paul

Journal:

Year:

2019

Language:

english

File:

PDF, 4.24 MB

english, 2019

18

Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions

Balkenhohl, Moritz, Ziegler, Dorothée S., Desaintjean, Alexandre, Bole, Leonie J., Kennedy, Alan R., Hevia, Eva, Knochel, Paul

Journal:

Angewandte Chemie International Edition

Year:

2019

Language:

english

File:

PDF, 1.47 MB

english, 2019

19

Cobalt‐Catalyzed Cross‐Couplings and Electrophilic Aminations using Organozinc Pivalates

Lutter, Ferdinand H., Graßl, Simon, Grokenberger, Lucie, Hofmayer, Maximilian S., Chen, Yi‐Hung, Knochel, Paul

Journal:

Year:

2019

Language:

english

File:

PDF, 1022 KB

english, 2019

20

A Predictive Model Towards SiteâSelective Metalations of Functionalized Heterocycles, Arenes, Olefins and Alkanes using TMPZnClÂ·LiCl

Balkenhohl, Moritz, Jangra, Harish, Makarov, Ilya S., Yang, Shu-Mei, Zipse, Hendrik, Knochel, Paul

Journal:

Angewandte Chemie International Edition

Year:

2020

File:

PDF, 2.08 MB

2020

21

Preparation of Highly Functionalized Grignard Reagents by an Iodine–Magnesium Exchange Reaction and its Application in Solid-Phase Synthesis

Laure Boymond, Mario Rottländer, Gérard Cahiez, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

1998

Language:

english

File:

PDF, 107 KB

english, 1998

22

Ferrocenyl Ligands with Two Phosphanyl Substituents in the α,ε positions for the Transition Metal Catalyzed Asymmetric Hydrogenation of Functionalized Double Bonds

Tania Ireland, Gabriele Grossheimann, Catherine Wieser-Jeunesse, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

1999

Language:

english

File:

PDF, 145 KB

english, 1999

23

Carbocupration/Zinc Carbenoid Homologation and β-Elimination Reactions for a New Synthesis of Allenes − Application to the Enantioselective Synthesis of Chiral Allenes by Deracemization of sp3-Organometallic Derivatives

Jos P. Varghese, Irena Zouev, Lionel Aufauvre, Paul Knochel, Ilan Marek

Journal:

European Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 165 KB

english, 2002

24

A LiCl-Mediated Br/Mg Exchange Reaction for the Preparation of Functionalized Aryl- and Heteroarylmagnesium Compounds from Organic Bromides

Arkady Krasovskiy, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2004

Language:

english

File:

PDF, 145 KB

english, 2004

25

Mixed Mg/Li Amides of the Type R2NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium Compounds

Arkady Krasovskiy, Valeria Krasovskaya, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2006

Language:

english

File:

PDF, 119 KB

english, 2006

26

Direct Magnesiation of Polyfunctionalized Arenes and Heteroarenes Using (tmp)2Mg⋅2 LiCl

Giuliano C. Clososki, Christoph J. Rohbogner, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 142 KB

english, 2007

27

A General Method for meta and para Functionalization of Arenes Using TMP2Mg⋅2 LiCl

Christoph J. Rohbogner, Giuliano C. Clososki, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2008

Language:

english

File:

PDF, 363 KB

english, 2008

28

Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp-Zinc and tmp-Magnesium Bases with BF3⋅OEt2

Milica Jaric, Benjamin A. Haag, Andreas Unsinn, Konstantin Karaghiosoff, Paul Knochel

Journal:

Angewandte Chemie International Edition

Year:

2010

Language:

english

File:

PDF, 377 KB

english, 2010

29

Synthesis of Polyfunctional Allenes by Successive Copper-Mediated Substitutions

Matthias A. Schade, Dr. Shigeyuki Yamada, Prof. Dr. Paul Knochel

Journal:

Chemistry - A European Journal

Year:

2011

Language:

english

File:

PDF, 272 KB

english, 2011

30

ChemInform Abstract: Cesium Hydroxide Catalyzed Addition of Alcohols and Amine Derivatives to Alkynes and Styrene.

Dimitrios Tzalis, Christopher Koradin, Paul Knochel

Journal:

Year:

1999

File:

PDF, 30 KB

1999

31

Preparation of functionalized zinc and copper organometallics containing sulfur functionalities at the alpha or gamma position

Sidduri AchyuthaRao, Charles E. Tucker, Paul Knochel

Journal:

Tetrahedron Letters

Year:

1990

Language:

english

File:

PDF, 282 KB

english, 1990

32

A new preparation of highly functionaized aromatic and heteroaromatic zinc and copper organometallics

Tahir N. Majid, Paul Knochel

Journal:

Tetrahedron Letters

Year:

1990

Language:

english

File:

PDF, 297 KB

english, 1990

33

Stereoselective preparation of phosphine oxides via a 2,3-sigmatropic shift of allylic diphenylphosphinites

Stéphane Demay, Klaus Harms, Paul Knochel

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 240 KB

english, 1999

34

Cesium hydroxide catalyzed addition of alcohols and amine derivatives to alkynes and styrene

Dimitrios Tzalis, Christopher Koradin, Paul Knochel

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 177 KB

english, 1999

35

Highly diastereoselective Csp3–Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds

Thaler, Tobias, Haag, Benjamin, Gavryushin, Andrei, Schober, Katrin, Hartmann, Evelyn, Gschwind, Ruth M., Zipse, Hendrik, Mayer, Peter, Knochel, Paul

Journal:

Nature Chemistry

Year:

2010

Language:

english

File:

PDF, 1.74 MB

english, 2010

36

Stereoselective SN2-Substitutions Using Polyfunctional Lithium Arylcuprates Prepared by an Iodine−Copper Exchange

Calaza, M. Isabel, Yang, Xiaoyin, Soorukram, Darunee, Knochel, Paul

Journal:

Organic Letters

Year:

2004

Language:

english

File:

PDF, 74 KB

english, 2004

37

Preparation of Polyfunctional Aryl Azides from Aryl Triazenes. A New Synthesis of Ellipticine, 9-Methoxyellipticine, Isoellipticine, and 7-Carbethoxyisoellipticine

Liu, Ching-Yuan, Knochel, Paul

Journal:

Journal of Organic Chemistry

Year:

2007

Language:

english

File:

PDF, 266 KB

english, 2007

38

Regio- and Chemoselective Multiple Functionalization of Chloropyrazine Derivatives. Application to the Synthesis of Coelenterazine

Mosrin, Marc, Bresser, Tomke, Knochel, Paul

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 515 KB

english, 2009

39

New Efficient Nickel- and Palladium-Catalyzed Cross-Coupling Reactions Mediated by Tetrabutylammonium Iodide

Piber, Michael, Jensen, Anne Eeg, Rottländer, Mario, Knochel, Paul

Journal:

Organic Letters

Year:

1999

Language:

english

File:

PDF, 49 KB

english, 1999

40

t-BuOK-Catalyzed addition of ketones and nitriles to vinylic silanes, phosphines and thio derivatives

Bunlaksananusorn, Tanasri, Rodriguez, Alain Louis, Knochel, Paul

Journal:

Chemical Communications

Year:

2001

Language:

english

File:

PDF, 44 KB

english, 2001

41

Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents

Muñoz Hernandez, Carmen, Manolikakes, Georg, Schade, Matthias A., Metzger, Albrecht, Knochel, Paul

Journal:

Journal of Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 642 KB

english, 2008

42

Preparation and reactions of polyfunctional organozinc reagents in organic synthesis

Knochel, Paul., Singer, Robert D.

Journal:

Chemical Reviews

Year:

1993

Language:

english

File:

PDF, 4.94 MB

english, 1993

43

Direct preparation of polyfunctional amino-substituted arylmagnesium reagents via an iodine–magnesium exchange reaction

Varchi, Greta, Kofink, Christiane, Lindsay, David M., Ricci, Alfredo, Knochel, Paul

Journal:

Chemical Communications

Year:

2003

Language:

english

File:

PDF, 106 KB

english, 2003

44

Stereoselective Preparation of Functionalized Acyclic Alkenylmagnesium Reagents Using i- PrMgCl·LiCl

Ren, Hongjun, Krasovskiy, Arkady, Knochel, Paul

Journal:

Organic Letters

Year:

2004

Language:

english

File:

PDF, 59 KB

english, 2004

45

Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl·LiCl

Bresser, Tomke, Monzon, Gabriel, Mosrin, Marc, Knochel, Paul

Journal:

Organic Process Research & Development

Year:

2010

Language:

english

File:

PDF, 195 KB

english, 2010

46

Preparation of New Polyfunctional Magnesiated Heterocycles Using a Chlorine−, Bromine−, or Iodine−Magnesium Exchange

Abarbri, Mohamed, Thibonnet, Jérôme, Bérillon, Laurent, Dehmel, Florian, Rottländer, Mario, Knochel, Paul

Journal:

Journal of Organic Chemistry

Year:

2000

Language:

english

File:

PDF, 434 KB

english, 2000

47

Isoreticular Two-Dimensional Covalent Organic Frameworks Synthesized by On-Surface Condensation of Diboronic Acids

Dienstmaier, Jürgen F., Medina, Dana D., Dogru, Mirjam, Knochel, Paul, Bein, Thomas, Heckl, Wolfgang M., Lackinger, Markus

Journal:

Year:

2012

Language:

english

File:

PDF, 1.52 MB

english, 2012

48

[Topics in Current Chemistry] Modern Solvents in Organic Synthesis Volume 206 || Reactions in Supercritical Carbon Dioxide (scCO2)

Year:

1999

Language:

english

File:

PDF, 330 KB

english, 1999

49

Grignard Reagents: Alkoxide-Directed Iodine−Magnesium Exchange at sp 3 Centers

Fleming, Fraser F., Gudipati, Subrahmanyam, Vu, Viet Anh, Mycka, Robert J., Knochel, Paul

Journal:

Organic Letters

Year:

2007

Language:

english

File:

PDF, 61 KB

english, 2007

50

A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene

Dogru, Mirjam, Handloser, Matthias, Auras, Florian, Kunz, Thomas, Medina, Dana, Hartschuh, Achim, Knochel, Paul, Bein, Thomas

Journal:

Angewandte Chemie International Edition

Year:

2013

Language:

english

File:

PDF, 1.00 MB

english, 2013